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How does calcium formate reduce carbon dioxide emissions?

How does calcium formate reduce carbon dioxide emissions?

2025-08-26

The reason why calcium formate can include "carbon reduction" in the process sheet is that it turns two types of waste gases that would otherwise turn into CO ₂ into raw materials.

 

More than 80% of the tail gas from steel mills or yellow phosphorus furnaces is carbon monoxide (CO), which used to only be ignited and released. 1 m ³ of CO ultimately generates 1.57 kg of CO ₂; Nowadays, after purification, CO is carbonylated with carbide slag (Ca (OH) ₂) at 1.5-6 MPa and 170-200 ℃ to obtain Ca (HCOO) ₂ in one step. CO is no longer burned and is directly "stored" in the product, with a carbon locking capacity of approximately 0.38 tons per ton of calcium formate.

 

The traditional neutralization method involves the reaction of calcium carbonate and formic acid, resulting in a by-product of 0.44 tons of CO ₂ per ton of product; The tail gas carbonyl method does not have this side reaction, and the process comparison life cycle assessment shows a 20% reduction in global warming potential.

 

Taking a 50000 ton plant as an example, it digests 45000 Nm ³/h converter gas annually, which is equivalent to reducing CO2 emissions by 52400 tons; If calculated at a carbon price of 90 yuan/ton, carbon assets alone are worth 27 million yuan/year.

 

In short, calcium formate has turned the CO and waste residue that should have been emptied into high value-added products through a closed-loop path of "treating waste with waste", providing quantifiable and tradable carbon reduction solutions for industries such as steel and phosphorus chemicals.